Pretty straightforward.

Install the necessary packages

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apt-get --no-install-recommends install nfs-kernel-server

Create virtual root

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mkdir /nfs # can be /srv, /export or whatever

Create a directory (or more) under virtual root directory

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mkdir /nfs/home 

Mount filesystems to be exported under virtual root directory

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mount --bind /home /nfs/home 

Make the mount points persistent. Append them to /etc/fstab.

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/home /nfs/home none bind 0 0 

Put the following in /etc/exports (assuming access is granted to the clients in the 192.0.2.0/24 IP network. Client access can also be specified as a single host using IP address or fully qualified domain name, or * character to grant access to all clients).

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/nfs 192.0.2.0/24(insecure,rw,sync,no_subtree_check,crossmnt,fsid=0)
/nfs/home 192.0.2.0/24(insecure,rw,sync,no_subtree_check)

Configure the daemon. Edit /etc/conf.d/nfs

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OPTS_RPC_NFSD="8 -N 2 -V 3 -V 4 -V 4.1"

Start NFS server (assuming OpenRC. See your init system’s documentation)

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rc-service nfs-kernel-server start 

Start NFS server at boot

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rc-update add nfs-kernel-server default

See detailed (and more) instructions on Gentoo wiki.